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Question: What kind of materials do i need to clean a quite valuable!?
watercolour painting without harming it!.

Best Answer - Chosen by Asker:
Quite right! Don't do anything to the painting!.

Maybe the painting can look better with a new mount!?

If there is mould on the watercolour, Art gallery conservations sometimes leave the painting in sunlight to kill the mould spores!. If the painting is valuable take it to a qualified resorer!. The Art Gallery should be able to give you a list of reputable restorers!.Www@QuestionHome@Com

Do NOT try to do this yourself!. Anything you put on it will either destroy the painting itself, or the paper it was painted on!.
As someone else suggested, an art restorer would be the best bet!. They have the expertise to clean a piece of art!. To find a restorer, contact art galleries and museums!.Www@QuestionHome@Com

Don't even think about! Any solvent will attack the watercolour!.Www@QuestionHome@Com